Toxic VOCs released from consumer products

A new study by the Silent Spring Institute and the University of California, Berkeley in the US has exposed how much people come into contact with toxic ingredients in products, used at home and at work, that could harm their health. Findings from the analysis, published in the journal Environmental Science & Technology, could help state and federal agencies strengthen chemical regulations and guide manufacturers in making safer products.

Many common products like shampoos, body lotions, cleaners, mothballs and paint removers contain toxic volatile organic compounds (VOCs) — chemicals that escape as gases, accumulate in indoor air and cause a variety of health problems including cancer. Because companies, for the most part, are not required to disclose what it’s in their products or how much, it’s difficult to know what people might be exposed to and the potential health effects.

For the new analysis, Silent Spring scientist Kristin Knox and her colleagues turned to an unlikely source of data: the California Air Resources Board (CARB). For more than 30 years, CARB has been tracking VOCs in consumer products in an effort to reduce smog. In the presence of sunlight, VOCs react with other air pollutants to form ozone, the main ingredient in smog.

Under its Consumer Product Regulatory program, CARB periodically surveys companies that sell products in California, collecting information on a wide range of items — everything from hairspray to windshield wiper fluid. The data include information on the concentration of VOCs used in various types of products and how much of each product type is sold in the state. CARB does not share data on specific products.

The researchers analysed the most recent CARB data, focusing on 33 VOCs listed under California’s right-to-know law, Prop 65, because they cause cancer, birth defects or other reproductive harm. The law requires companies that sell products in California to warn users if their products could expose them to significant amounts of these harmful chemicals.

The team’s analysis found more than 100 types of products contain Prop 65 VOCs. Of those, the researchers identified 30, including a dozen different types of personal care products, that deserve special scrutiny because they frequently contain harmful chemicals and may pose the greatest health risk. (Since CARB only reports on VOCs, many other toxic chemicals listed under Prop 65, such as lead, were not included in the analysis.)

Products used on the job are especially concerning, the authors noted, because workers often use many different types of products, each of which likely contains at least one hazardous chemical. For instance, nail and hair salon workers use nail polishes and polish removers, artificial nail adhesives, hair straighteners and other cosmetics. According to the analysis, these types of products combined contain as many as nine different Prop 65 VOCs. Cleaners might use a combination of general cleaners, degreasers, detergents and other maintenance products, which could expose them to more than 20 Prop 65 VOCs.

“The same thing goes for auto and construction workers; all these exposures add up and might cause serious harm,” said co-author and study leader Meg Schwarzman, from UC Berkeley. “At the most basic level, workers deserve to know what they’re exposed to. But, ultimately, they deserve safer products and this study should compel manufacturers to make significant changes to protect workers’ health.”

Of the 33 VOCs listed under Prop 65, the researchers identified the top 11 chemicals that manufacturers should eliminate from products because of the chemicals’ high toxicity and widespread use. Other findings include:

• Among products used on the body, formaldehyde was the most common Prop 65 VOC, and was found in nail polish, shampoo, make-up and other types of personal care items.
• For products used in the home, general-purpose cleaners, art supplies and laundry detergents contained the most Prop 65 VOCs.
• Adhesives contained more than a dozen different Prop 65 VOCs, highlighting that workers can be exposed to many toxic chemicals from using just one type of product.
   

Finally, the team used the CARB data to calculate the total amount of Prop 65 VOCs emitted from consumer products indoors and found more than 5000 tons of volatile Prop 65 chemicals were released from products in the state of California in 2020. Nearly 300 tons of that came from mothballs (1,4-dichlorobenzene) alone.

“Although Prop 65 has reduced the public’s exposure to toxic chemicals both through litigation and by incentivising companies to reformulate their products, people continue to be exposed to many unsafe chemicals,” said co-author Claudia Polsky, Director of the Environmental Law Clinic at UC Berkeley School of Law. “This study shows how much work remains for product manufacturers and regulators nationwide, because the products in CARB’s database are sold throughout the US.”

In addition to highlighting the types of products manufacturers should reformulate to replace toxic VOCs with safer ingredients, the authors also suggest that the US Environmental Protection Agency consider regulating five additional chemicals under the Toxic Substances Control Act (TSCA). These chemicals include ethylene oxide, styrene, 1,3-dichloropropene, diethanolamine and cumene.

“This study is the first to reveal the extent to which toxic VOCs are used in everyday products of all types that could lead to serious health problems,” Knox said. “Making this information public could incentivise manufacturers to reformulate their products and use safer ingredients.”

Illustration credit: Meg Schwarzman, UC Berkeley.